Crystal structure of bis{(Z)-(benzylamino)[(5Z)-2-(benzylimino-κN)-5-(2-methoxy-2-oxoethylidene)-4-oxothiolan-3-ylidene]methanethiolato-κS}copper(II)
نویسندگان
چکیده
The title complex, [Cu(C22H19N2O3S2)2], was obtained from the reaction between (Z)-methyl 2-(5-benzyl-imino-4-benzyl-carbamo-thioyl-3-oxo-thio-lan-2-yl-idene)acetate and Cu(NO3)2. The Cu(II) atom is tetra-coordinated by two N,S-bidentate ligands, forming a highly distorted tetra-hedral environment. The structure displays two intra-molecular N-H⋯O hydrogen bonds.
منابع مشابه
(Anilino{(Z)-2-[(E)-5-bromo-3-methoxy-2-oxidobenzylidene]hydrazin-1-ylidene-κ2 O 2,N 2}methanethiolato-κS)(4,4′-dimethyl-2,2′-bipyridine-κ2 N,N′)zinc N,N-dimethylformamide monosolvate
The asymmetric unit of the title compound, [Zn(C(15)H(12)BrN(3)O(2)S)(C(12)H(12)N(2))]·C(3)H(7)NO, contains two independent mol-ecules with a similar structure. The doubly deprotonated Schiff base ligand O,N,S-chelates to the metal atom, and the three coordinating atoms along with one N atom of the substituted 2,2'-bipyridine ligand constitute the square plane of the distorted square pyramid su...
متن کاملDimethyl (2Z)-2-[4-((1Z)-1-{2-[(2Z,5Z)-5-(2-methoxy-2-oxoethylidene)-4-oxo-3-phenyl-1,3-thiazolidin-2-ylidene]hydrazin-1-ylidene}ethyl)anilino]but-2-enedioate
The mol-ecule of the title compound, C26H24N4O7S, adopts a trans conformation about the central N-N bond, presumably to minimize steric between the substituents on these two atoms. An intra-molecular N-H⋯O hydrogen bond occurs. The phenyl ring is disordered over two sets of sites, with an occupancy ratio of 0.624 (8):0.376 (8). The azolidine ring is essentially planar [maximum deviation = 0.008...
متن کاملIodido[1-(propan-2-ylidene)thiosemicarbazide-κS]bis(triphenylphosphane-κP)copper(I)
In the mononuclear title complex, [CuI(C(4)H(9)N(3)S)(C(18)H(15)P)(2)], the Cu(I) ion displays a distorted tetra-hedral coordination geometry involving two P atoms of two triphenyl-phosphane mol-ecules, one S atom of a 1-(propan-2-yl-idene)thio-semicarbazide mol-ecule and one iodide ion. In the crystal, C-H⋯π inter-actions [C-H⋯centroid distances = 3.443 (3) and 3.788 (3) Å] and N-H⋯S hydrogen ...
متن کاملDi-μ-methanolato-κ4 O:O-bis[bis(3-methyl-5-phenyl-1H-pyrazole-κN 2)(nitrato-κO)copper(II)]
Copper nitrate in methanol solution cleaves the N-C(methanol) bond when reacted with 3-methyl-5-phenyl-pyrazole-1-methanol to yield the centrosymmetric dinuclear title compound, [Cu(2)(CH(3)O)(2)(NO(3))(2)(C(10)H(10)N(2))(4)], in which the Cu(II) atom is linked to a nitrate ion, two methano-late ions and two pyrazole ligands in a distorted square-pyramidal environment. The O atom of the nitrate...
متن کاملCrystal structure of chlorido{1-(2,3-dimethyl-5-oxido-1-phenyl-1H-pyrazol-2-ium-4-yl-κO)-2-[3-methyl-5-oxo-1-phenyl-4,5-dihydro-1H-pyrazol-4-ylidene-κO]hydrazin-1-ido-κN 1}copper(II) from laboratory X-ray powder data
In the title compound, [Cu(C21H19N6O2)Cl], the Cu(II) atom is in a slightly distorted square-planar coordination involving two O atoms from the pyrazolone rings [Cu-O = 2.088 (10) and 1.975 (10) Å], an N atom of the azo group [Cu-N = 2.048 (13) Å] and a chloride anion [Cu-Cl = 2.183 (5) Å]. The organic anions act as tridentate chelating ligands. The mol-ecules stack in columns along the c axis.
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عنوان ژورنال:
دوره 71 شماره
صفحات -
تاریخ انتشار 2015